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納米金剛石膜/100晶面多晶金剛石膜臺階法快速生長研究

Fast fabrication of nanocrystalline and 100 faceted polycrystalline diamond films by using stepped method

  • 摘要: 通過高功率微波等離子體化學氣相沉積(MPCVD)以及臺階式基底排列方法,可以在一次沉積過程中同時沉積納米晶粒及<100>取向的100面多晶金剛石薄膜。詳細比較在同一次沉積中同時製備的多種不同類別的金剛石產物的生長速率🤾🏽‍♂️。采用臺階法並添加少量空氣🤾🏼‍♂️,微波功率從2.0 kW增加至3.2 kW⛄️,在下面大矽片上生長的納米金剛石膜的平均生長速率可從0.3 μm/h增大到3.0 μm/h🛻;而在上面小矽片上生長的納米金剛石膜的平均生長速率從3.8 μm/h也增加到11.2 μm/h👨🏼‍🚒,同時產物也轉變為100晶面的多晶膜👩🏻‍🏫。另外👨🏿‍🔧,在上面小矽片上生長的金剛石膜的邊角效應明顯🈯️,在邊界生長的金剛石產物的生長速率更高,從17.0 μm/h增大到27.1 μm/h。該結果表明少量氮氣和氧氣同時添加對金剛石生長的形貌多樣性調節作用和對生長速率的提升作用強烈依賴於生長條件🤽🏽‍♀️。

     

    Abstract: Nanocrystalline and <100> oriented 100 faceted polycrystalline diamond films can be deposited simultaneously in one deposition run by high power microwave plasma chemical vapor deposition (MPCVD) and using stepped method for substrate arrangement. Focus was made on comparing the difference on diamond products and their growth rate in one deposition run and among different growth processes. When microwave power was increased from 2.0 kW to 3.2 kW, the growth rate of nanocrystalline diamond (NCD) film grown on the bottom big Si wafer was enhanced from 0.3 μm/h up to 3.0 μm/h; while the growth rate for diamond products grown on the top small Si slices was 3.8 μm/h for NCD film at 2.0 kW and raised to 11.2 μm/h for <100> oriented 100 faceted large-grained polycrystalline diamond film at 3.2 kW. Furthermore, the diamond products near the edge and corner of the small Si slice are different from that grown on the center of the same substrate, namely the edge effect is pronounced, and the growth rate was further improved, ranging from 17.0 μm/h up to 27.1 μm/h. This work clearly demonstrates the versatility of N2 and O2 addition on diamond growth by using stepped method and further deepen the understanding of the complicated diamond growth process by high power MPCVD.

     

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