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稀土離子摻雜鈣鈦礦納米材料的光學性質及光電應用研究

Optical properties and optoelectronic applications of rare earth ion-doped perovskite nanomaterials

  • 摘要: 金屬鹵化物鈣鈦礦材料具備可調的可見光譜區帶隙、良好的載流子傳輸性能、長的電荷擴散長度、弱激子結合能、高吸收系數、高光電轉化效率、高缺陷容忍度、良好的催化性能和簡單的製備工藝等一系列獨特的理化性質,使其在多種新興光電技術領域備受關註。稀土離子具有豐富的4f能級躍遷效應,有望促使鈣鈦礦納米材料的吸收、激發和發射,從而表現出範圍寬且內涵豐富的量子行為和光電特性。面向實際光電應用的需求,稀土離子摻雜的鈣鈦礦納米材料能夠顯著提升鈣鈦礦納米材料的光電性質,解決鈣鈦礦納米材料難以直接在近紅外光區的應用,改善環境穩定性和含鉛毒性的不足。總結了稀土離子摻雜鈣鈦礦納米材料的結構性質、製備工藝、光學性質、穩定性及在光電領域應用的研究進展,並對其在新型光電技術領域的發展前景進行了展望。

     

    Abstract: Metal halide perovskite materials have attracted much attention in various emerging optoelectronic technology fields because of a series of unique physical and chemical properties such as tunable band gap in the visible spectrum, good carrier transmission performance, long charge diffusion length, weak exciton binding energy, high absorption coefficient, high photoelectric conversion efficiency, high defect tolerance, good catalytic performance and simple preparation process. Rare earth ions have rich 4f energy level transition effects, which are expected to promote the absorption, excitation and emission of perovskite nanomaterials, thus showing a wide range of quantum behavior and photoelectric properties with rich content. In light of the needs of practical photoelectric applications, rare earth ion-doped perovskite nanomaterials can significantly improve the photoelectric properties of perovskite nanomaterials, solve the problems of direct application of perovskite nanomaterials in the near-infrared region and improve environmental stability and lead toxicity. The research progress on the structural properties, preparation process, optical properties, stability and application of rare earth ion-doped perovskite nanomaterials for optoelectronic applications were summarized, and their development prospects in the field of new optoelectronic technologies were proposed.

     

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