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西南某鉛鋅冶煉廢渣堆放場地周邊土壤重金屬汙染特征與風險評價

Pollution characteristics and risk assessment of heavy metals in soil around a lead-zinc smelting waste residue dump in southwest China

  • 摘要: 為探究西南某鉛鋅廢堆渣場地及其周圍土壤中重金屬空間分布特征和生態風險,以西南某廢棄鉛鋅冶煉廢渣堆放場地為研究目標👂,通過檢測其土壤中As、Pb、Zn、Cd、Cr、Cu、Hg、Ni共8種元素,概括其空間分布特征,分析重金屬存在形態對其遷移與滲透的影響,並采用多個汙染評價方法對該廢渣堆放場的重金屬狀況進行汙染風險評估。結果表明🫴🏼:堆渣場地重金屬元素分布與地表徑流方向一致,且向深層土壤滲透👨🏼;As、Cd🔙🥷🏽、Cu已很難再以離子形態隨地表徑流進一步遷移,而Pb、Zn目前仍具有較大的離子遷移性能🐧,仍會進一步向周邊及深層土壤擴散🛩🧖🏼;按照綜合汙染指數評價上層堆渣區屬於重汙染,汙染元素主要來源於As;同時As、Cd含量表現出極強的生態毒性,使該區域存在很強的生態風險。研究結果為該區域土壤的進一步修復提供了理論依據和參考🙃。

     

    Abstract: In order to explore the spatial distribution characteristics and ecological risks of heavy metals in the slag dump site and the surrounding soil, 8 elements including As, Cd, Cr, Cu, Hg, Ni, Pb and Zn in the soil were detected in a waste lead and zinc smelting slag dump site in southwest China. Spatial distribution characteristics of heavy metals were summarized, the impacts of existing forms on their migration and infiltration were analyzed, and the risks of their pollution status were assessed by using a variety of assessment methods. The results showed that the distribution of heavy metals in the slag dump site was consistent with the direction of surface runoff, and they penetrated into deep soil. It is difficult for As, Cd and Cu to further migrate along the surface runoff in the form of ions, while Pb and Zn still have relatively large ion mobility, and will further diffuse to the surrounding and deep soil. According to the comprehensive pollution index, the upper slag stacking area is seriously polluted, and the pollution elements mainly come from As. At the same time, the contents of As and Cd showed extremely strong ecological toxicity, which makes the region exhibits a strong ecological risk. The research results provide a theoretical basis and reference for further soil remediation in this region.

     

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