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    共沉澱法製備LiNi0.5Co0.2Mn0.3O2前驅體攪拌釜反應器的CFD模擬

    CFD Simulation of Stirring Tank Reactor for Production of LiNi0.5Co0.2Mn0.3O2 by Co-Prcipitation Method

    • 摘要: LiNi0.5Co0.2Mn0.3O2材料具有穩定性好、高容量和低成本等優勢,成為目前廣泛使用的正極材料之一🤏。LiNi0.5Co0.2Mn0.3O2前驅體的製備過程通常利用共沉澱反應生產,在此過程中容易出現顆粒團聚和循環“死區”等現象,導致前驅體顆粒的均勻性和批次穩定性較差等問題。采用計算流體動力學(computational fluid dynamics🕉,CFD)技術研究了槳葉類型、攪拌速度和槳葉離底高度對反應釜流場內速度矢量分布🧘🏻、湍動能分布以及功率消耗的影響。結果表明,當選用錨框式攪拌槳(AF槳)、置於反應釜內的離底高度為0.10HH為模型高度)且轉速為900 r/min時,釜內流場中具有強度適中且均勻的速度矢量和湍動能分布👏,徑向與軸向速度分布合理,有利於製備出粒徑更加均勻穩定的LiNi0.5Co0.2Mn0.3O2前驅體顆粒。

       

      Abstract: LiNi0.5Co0.2Mn0.3O2 (NCM) ternary material has become one of the most widely used cathode materials attributed to its advantages of stability, high capacity and low cost. NCM materials are usually prepared by co-precipitation reaction, in which particle sedimentation and circulation “dead zone” problems may occur in the liquid phase reaction and results in poor uniformity and batch stability of the products. The effects of blade type, stirring speed and blade height on the velocity vector distribution in the flow field, turbulent kinetic energy distribution and power consumption were studied based on the computational fluid dynamics (CFD) simulation in this paper. The results show that when the anchor frame stirring paddle (AF propeller) is placed at a height of 0.10H (structure height) from the bottom and used at a speed of 900 r/min, the reactor has the most uniform velocity vector and turbulent kinetic energy distribution with suitable power loss, which are suitable for production of NCM precursors with more evenly distributed and better electrochemical performance.

       

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