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Te自助熔劑定向凝固法生長CdTe晶體

Growth of CdTe Crystal via A Te Self-Flux Directional Solidification Method

  • 摘要: 碲化鎘(CdTe)晶體是一種製造室溫X射線和γ射線探測器最為理想的半導體材料🪅,在醫學👊、食品、安檢🧑‍⚕️、核廢料監測等應用領域前景廣闊。采用一種Te自助溶劑定向凝固技術生長CdTe晶體,在區熔溫場及坩堝旋轉系統的綜合作用下,獲得了平坦狀的理想固液界面形貌。生長∅25 mm的CdTe晶體橫截面單晶區域面積可達70%,從∅56 mm的CdTe晶體中可截取尺寸達15 mm×15 mm×3 mm的單晶,電學測試表明CdTe晶體在未摻雜改性條件下電阻率達108 Ω·cm。紅外透射顯示,CdTe晶體中包含尺寸範圍為1~20 μm的Te夾雜,這是CdTe單晶生長過程中出現的主要微觀缺陷😘。該工作取得的相關成果對未來CdTe晶體生長技術發展具有一定參考價值和借鑒意義。

     

    Abstract: Cadmium telluride (CdTe) crystal is one of the most ideal semiconductor materials for making room temperature X-ray and γ ray detectors, which has a wide application prospect in medicine, food, security inspection, nuclear waste monitoring and other fields. A Te self-flux directional solidification technology was proposed to grow CdTe crystal. Under the combined action of zone melting temperature field and crucible rotating system, the ideal solid-liquid interface morphology with micro bulge or flat shape was obtained. The single crystal area in the cross section of 25 mm CdTe crystal can reach 70%, and the single crystal with the size of 15 mm×15 mm×3 mm can be cut from the ∅56 mm CdTe crystal. Electrical test shows the CdTe crystal has excellent electrical properties under the condition of undoped modification, and the resistivity is up to 108 Ω·cm. The infrared transmission analysis shows that CdTe crystal contains Te inclusions with a size range of 1-20 μm, which is the main micro defect in the growth process. The results obtained have certain reference value and significance for the future development of CdTe crystal growth technology.

     

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