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鎂合金的微弧氧化:輕量化材料評述

Micro-Arc Oxidation of Magnesium Alloys:Lightweight Materials Review

  • 摘要: 輕量化材料鎂合金能夠顯著降低電動汽車整備重量、從而延長行駛裏程並減少碳排放,應用前景十分廣泛。鎂合金的活性高,需采取表面處理技術使其表面不被腐蝕💠。微弧氧化是一種通過多參數聯合控製的濕法表面處理來提升鎂合金試件表層耐蝕性的工藝過程,通過這種工藝💂‍♀️🕞,試件的表面原位生成陶瓷保護膜。電壓脈沖方式、電流密度🪦、頻率和占空比等電參數和電解液特性均影響鎂合金表面陶瓷膜層的結構🚵🏼。鎂合金材料微弧氧化工藝具有清洗和前處理工藝簡單、對電解液組分和環境溫度不敏感、可以分段實施等優點🎢。現階段缺點為配套設施不完善,氧化電壓和系統能耗較高👮🏻,電解液溫度沒有冷卻和熱交換設備來進行有效控製。陶瓷膜生長的機理研究也需要進一步闡明。

     

    Abstract: Magnesium alloys are the most potential lightweight high-strength structural materials, which can significantly reduce the curb weight of electric vehicles, extend the driving range and reduce carbon emissions. However, magnesium alloys have high chemical activity and are easy to be corroded. Micro-arc oxidation is a wet surface treatment process controlled by multi parameters. By this way, a dense ceramic protective film can home-position grow up on the surface of magnesium alloys, which improves the corrosion resistance. Voltage pulse mode, current density, frequency and duty ratio and electrolyte characteristics can significantly affect the structure of ceramic coating on the surface of magnesium alloys. Micro-arc oxidation process has several advantages, such as simple cleaning and pretreatment, insensitivity to electrolyte composition and ambient temperature, and dividable implementation. The main challenges are that the supporting equipment need to be further improved, the oxidation voltage and system energy consumption are high, and the electrolyte temperature rises too fast so that it requires a large volume of cooling and heat exchange equipment. Furthermore, the growing mechanism of ceramic film should be clarified.

     

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